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Synthesis and Structure of [NaTi(2,6-Me2C6H3O)4(py)]2: a Dimeric Material Containing a Novel Phenoxide Bridge

✍ Scribed by Dr. Loren D. Durfee; Dr. Phillip E. Fanwick; Prof. Ian P. Rothwell


Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
243 KB
Volume
27
Category
Article
ISSN
0044-8249

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Synthesis and Structure of the Tetrameri
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Treating [Cp\*V(l-Cl) 2 ] 3 (Cp\* = C 5 Me 5 ) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoMe 2 ], respectively, with Me 3 SnF afforded the title compounds [Cp\*V(l-F) 2 ] 4 (1) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoF 2 ] Β΄THF ( 2). 1 has a tetrameric structure, in which four V atoms can be regarded as being arranged