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Synthesis of 2′,3′-dideoxy-3′-hydroxymethylcytidine: A novel hydroformylation route

✍ Scribed by Stephen W. Kaldor; James E. Fritz; Jeffrey A. Ward

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 168 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00142-1

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✦ Synopsis

2',3'-Dideoxy-3'-hydroxymethylcytidine (1) has been synthesized via stereoseleetive Rhcatalyzed hydroformylation of 2',3'-didehydro-2',3'-dideoxycytidine 3b. This synthesis incorporates the first successful hydroformylation of a nucleoside olefin.

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