Synthesis of 2-thiabicyclo[3.2.0]hept-3-enes by reaction of acetylene with sodium sulfide
β Scribed by B. A. Trofimov; G. A. Kalabin; V. V. Kryuchkov; V. V. Keiko; S. V. Amosova; V. M. Bzhezovskii; V. K. Voronov; D. F. Kushnarev; V. Yu. Vitkovskii; L. I. Lavlinskaya; V. A. Pestunovich
- Book ID
- 112330022
- Publisher
- Springer US
- Year
- 1976
- Tongue
- English
- Weight
- 303 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0009-3122
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Three new compounds, one with the mo~ecular formula c6&s and hvo COmspOnding to GHloS have been isolated together with the main product, divinyl sulphide, from the reaction products of acetylene with sodium sulphide. Structure determination through 'H and 13C NMR with selective "C4'H) decoupling, sh
m Aminobicyclo (3.2.0) heptenones and aminonorbornenones were obtained from methylacrylate or acrylonitrile and captodative dienes. They result from respectively (2+2) and (4+2) cycloadditions.