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Synthesis of 2-Amino-2-deoxy-L-Arabinose (L-Arabinosamine)

✍ Scribed by Wolfrom, M. L.; Yosizawa, Z.


Book ID
126179592
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
262 KB
Volume
81
Category
Article
ISSN
0002-7863

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Efficient syntheses of l-ribose and 2-de
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Interconversion of the ends of D-ribese 2 afforded in 6 steps and 45% overall yield L-ribose 1, from which 2-deoxy L-ribose 12 was easily prepared. In addition, the inexpensive L-arabinose 13 was also converted into 2-deoxy L-ribose 12 via a reductive radical rearrangement of the arabinopyranosyl br