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Efficient syntheses of l-ribose and 2-deoxy l-ribose from d-ribose and l-arabinose

โœ Scribed by Michael E. Jung; Yue Xu

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
204 KB
Volume
38
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Interconversion of the ends of D-ribese 2 afforded in 6 steps and 45% overall yield L-ribose 1, from which 2-deoxy L-ribose 12 was easily prepared. In addition, the inexpensive L-arabinose 13 was also converted into 2-deoxy L-ribose 12 via a reductive radical rearrangement of the arabinopyranosyl bromide 14.

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