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The total syntheses of 2-deoxy-DL- and L-riboses

✍ Scribed by Gen Nakaminami; Masazumi Nakagawa; Sachiko Shioi; Yoko Sugiyama; Satoko Isemura; Mikio Shibuya

Publisher: Elsevier Science
Year: 1967
Tongue: French
Weight: 210 KB
Volume: 8
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)89765-3

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✦ Synopsis

We report herein the total synthe.ses of 2-deoxy-DL-and L-rlboses. As Illustrated in the following scheme, the Reformatsky reaction of ethyl bromoaoetate with aoroleln afforded the p-hydroxy eater (I) in a yield of 40-502, whloh was hydrolysed by means of aqueous potassium hydroxide to give the DL-acid (II, 85s yield). The hydroxy acid (II) in an aqueous solution was treated with

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