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Synthesis of 2-amino-1,3-dienes by chromium-catalyzed addition of silylated propargyl bromides to imines

✍ Scribed by María Durán-Galván; Brian T. Connell

Book ID
113928852
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
797 KB
Volume
67
Category
Article
ISSN
0040-4020

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Conjugated exocyclic dienes by addition
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✍ J. van der Louw; M. Slagt; J.L. van der Baan; F. Bickelhaupt; G.W. Klumpp 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 187 KB

## Reaction of 2-(benzyloxymethyl)-3-(bromozincmethyl)-I ,3-butadiene with aldehydes, ketones and imines afforded addition products 6, which underwent Pd(O)-catalyzed cyclization to the conjugated exocyclic dienes 7.