Diels-alder additions of 1,3-dienes to propargylic alcohols catalyzed by the Wilkinson's catalyst
✍ Scribed by Renko Zafiarisoa Dolor; Pierre Vogel
- Publisher
- Elsevier Science
- Year
- 1990
- Weight
- 318 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0304-5102
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The Diels–Alder addition of acrolein to cyclohexa‐1,3‐diene has been studied between 486 and 571°K at pressures ranging from 55 to 240 torr. The products are endo‐ and exo‐5‐formylbicyclo[2.2.2]oct‐2‐ene (endo‐ and exo‐FBO), and their formations are second order. The rate constants (in
## Abstract The addition of ethene to cyclohexa‐1,3‐diene has been studied between 466 and 591 K at pressures ranging from 27 to 119 torr for ethene and 10 to 74 torr for cyclohexa‐1,3‐diene. The reaction is of the “Diels–Alder” type and leads to the formation of bicyclo[2.2.2]oct‐2‐ene. It is homo