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Diels-alder additions of 1,3-dienes to propargylic alcohols catalyzed by the Wilkinson's catalyst

✍ Scribed by Renko Zafiarisoa Dolor; Pierre Vogel


Publisher
Elsevier Science
Year
1990
Weight
318 KB
Volume
60
Category
Article
ISSN
0304-5102

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📜 SIMILAR VOLUMES


Kinetics of the Diels–Alder addition of
✍ G. Huybrechts; G. Paternoster; P. Baetens 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 360 KB 👁 1 views

## Abstract The Diels–Alder addition of acrolein to cyclohexa‐1,3‐diene has been studied between 486 and 571°K at pressures ranging from 55 to 240 torr. The products are endo‐ and exo‐5‐formylbicyclo[2.2.2]oct‐2‐ene (endo‐ and exo‐FBO), and their formations are second order. The rate constants (in

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## Abstract The addition of ethene to cyclohexa‐1,3‐diene has been studied between 466 and 591 K at pressures ranging from 27 to 119 torr for ethene and 10 to 74 torr for cyclohexa‐1,3‐diene. The reaction is of the “Diels–Alder” type and leads to the formation of bicyclo[2.2.2]oct‐2‐ene. It is homo