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Synthesis of 1,3-oxazolidines by copper-catalyzed addition of acetone and ethyl diazoacetate to imines

โœ Scribed by Seung-Han Lee; Jin Yang; Tae-Dong Han

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
77 KB
Volume
42
Category
Article
ISSN
0040-4039

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Synthesis of 1,3-oxazolidines from imine
Synthesis of 1,3-oxazolidines from imines and epoxides catalyzed by samarium compounds
โœ Takayuki Nishitani; Hiroyuki Shiraishi; Satoshi Sakaguchi; Yasutaka Ishii ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 154 KB

A new method for the synthesis of 1,3-oxazolidine derivatives has been developed. Thus, a variety of 1,3oxazolidines was prepared by the reaction of imines with epoxides in the presence of a catalytic amount of a samarium compound such as SmI 2 , SmI 3 , or Cp\* 2 Sm(thf) 2 .