Enantioselectivity and cis/trans-Selecti
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Paul MΓΌller; Corine Baud; DoΓ―na EnΓ©; Sharokh Motallebi; Michael P. Doyle; Bridge
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Article
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1995
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John Wiley and Sons
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German
β 741 KB
The Rh"-catalyzed carbenoid addition of diazoacetates to olefins was investigated with [Rh2{(4S)-phox},] (1; phox = tetrakis[(4S)-tetrahydro-4-phenyloxazol-2-one]), [Rh2{(2S)-mepy},] (2; mepy = tetrakis[methyl (2s)tetrahydro-5-oxopyrrole-2-carboxylate]), and [Rh,(OAc),] (3). While catalysis with 2 a