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Copper-Catalyzed Addition of Ethyl Diazoacetate to Furans: An Alternative to Dirhodium(II) Tetraacetate.

✍ Scribed by Ana Caballero; M. Mar Diaz-Requejo; Swiatoslaw Trofimenko; Tomas R. Belderrain; Pedro J. Perez


Publisher
John Wiley and Sons
Year
2005
Weight
39 KB
Volume
36
Category
Article
ISSN
0931-7597

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The Rh"-catalyzed carbenoid addition of diazoacetates to olefins was investigated with [Rh2{(4S)-phox},] (1; phox = tetrakis[(4S)-tetrahydro-4-phenyloxazol-2-one]), [Rh2{(2S)-mepy},] (2; mepy = tetrakis[methyl (2s)tetrahydro-5-oxopyrrole-2-carboxylate]), and [Rh,(OAc),] (3). While catalysis with 2 a