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Synthesis of 1,5-dicarbonyl and related compounds from Baylis–Hillman adducts via Pd-mediated decarboxylative protonation protocol

✍ Scribed by Saravanan Gowrisankar; Ko Hoon Kim; Sung Hwan Kim; Jae Nyoung Kim

Book ID
104095750
Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
174 KB
Volume
49
Category
Article
ISSN
0040-4039

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✦ Synopsis

We prepared various 1,5-dicarbonyl and related compounds from Baylis-Hillman adducts by using a Pd-mediated decarboxylative protonation protocol.

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An efficient synthetic method of poly-substituted pyridines was developed. Various poly-substituted pyridines were prepared from the combination of Baylis-Hillman adducts (3 carbons), activated methylene compounds (2 carbons) and ammonium acetate (1 nitrogen) via [3+2+1] annulation protocol in good

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