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Synthesis of 1,4-diketones by fluoride-catalysed Michael addition and supported permanganate oxidation

โœ Scribed by Clark, James H.; Cork, David G.


Book ID
115314281
Publisher
The Royal Society of Chemistry
Year
1982
Tongue
English
Weight
171 KB
Volume
11
Category
Article
ISSN
0022-4936

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Olefin-Insertion Reaction Between the Carbonyls of Benzils; Formation of 1,4-Diketones by Michael Addition Catalyzed by Cyanide Ion. -A novel Michael addition type olefination-insertion reaction between the carbonyl groups of benzils (I) affording 1,4-diketones (III) is described. Cyanide ion is req