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Synthesis of 1,2,3-triazole and 1,2,3,4-tetrazole-fused glycosides and nucleosides by an intramolecular 1,3-dipolar cycloaddition reaction

✍ Scribed by Anegundi, Ramakrishna I.; Puranik, Vedavati G.; Hotha, Srinivas


Book ID
120431425
Publisher
Royal Society of Chemistry
Year
2008
Tongue
English
Weight
283 KB
Volume
6
Category
Article
ISSN
1477-0520

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Regiospecific synthesis of 2-allyl-1,2,3
✍ Shin Kamijo; Tienan Jin; Zhibao Huo; Yoshinori Yamamoto πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 129 KB

2-Allyl-1,2,3-triazoles were prepared by the palladium-catalyzed three component coupling (TCC) reaction of alkynes, allyl methyl carbonate and trimethylsilyl azide. A p-allylpalladium azide complex, which undergoes the 1,3-dipolar cycloaddition with alkynes, is proposed as a key intermediate in the