1-(Azidomethyl)benzotriazole and -5-phenyl-1,2,3,4-tetrazole as 1, 3-dipolar cycloaddition components
โ Scribed by Alan R. Katritzky; Clara N. Fali; Irina V. Shcherbakova; Sergei V. Verin
- Book ID
- 112131474
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1996
- Tongue
- English
- Weight
- 391 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0022-152X
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๐ SIMILAR VOLUMES
In the title compound, C 13 H 8 N 8 O 2 , the benzotriazole group forms a dihedral angle of 17.56 (12) with the tetrazole ring and conjugation exists between them. The nitrobenzene group lies perpendicular to the tetrazole ring and there is no conjugation.
## Abstract magnified image 1,3โDipolar cycloadditions of azomethine imines **3a** and **3b**, available by acidโcatalyzed treatment of 3โpyrazolidinone **1** with acetone (**2a**) and butyraldehyde (**2b**), respectively, were studied. Reactions of **3a** with DMAD (**4**) afforded a mixture of p