𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of 1,1-dilithio-2,2,3,3-tetramethylcyclopropane

✍ Scribed by Kawa, Hajimu; Manley, Bobby C.; Lagow, Richard J.


Book ID
126996019
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
287 KB
Volume
107
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Controlled Rearrangement of 2,3-Dilithio
✍ Adalbert Maercker; H. Wunderlich; Ulrich Girreser πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 340 KB πŸ‘ 1 views

Dilithio-2,5-dimethyl-2,4-hexadiene (4a) rearranges to the cross-conjugated 2,5-dimethylhexadienediyl dianion 11a. A mechanistic investigation proves the intermolecularity of this rearrangement, which is also observed when starting from 4b. The 3-lithio-2,5-dimethylhexadienyl anion 10a with

1,3-Dilithio-2-(diphenylmethylene)propan
✍ Victor J. Lillo; Cecilia GΓ³mez; Miguel Yus πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 French βš– 236 KB
Synthesis of 2,5-dilithio-1-methylimidaz
✍ Gideon Shapiro; Martin Marzi πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 French βš– 290 KB

C5 to C2 position migratiw of 2-trialkylsilyl and thiophctgd groups have bus observed upon lithhth at the Cs-position of cxxqwkg C2-subwituted l-muhylixnkko~. Double brominelithium exchange of I-mcthyL2$sle (5) affords a facile, qluwthive and uuequivocal synthc& of 2,5\_dilithio\_l~l-~~ (4). Raction