𝔖 Bobbio Scriptorium
✦   LIBER   ✦

1,3-Dilithio-2-(diphenylmethylene)propane

✍ Scribed by Victor J. Lillo; Cecilia Gómez; Miguel Yus


Book ID
108285076
Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
236 KB
Volume
49
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Controlled Rearrangement of 2,3-Dilithio
✍ Adalbert Maercker; H. Wunderlich; Ulrich Girreser 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 340 KB 👁 1 views

Dilithio-2,5-dimethyl-2,4-hexadiene (4a) rearranges to the cross-conjugated 2,5-dimethylhexadienediyl dianion 11a. A mechanistic investigation proves the intermolecularity of this rearrangement, which is also observed when starting from 4b. The 3-lithio-2,5-dimethylhexadienyl anion 10a with

1,4-Dilithio-1,3-butadienes
✍ Ashe, Arthur J.; Mahmoud, Samir. 📂 Article 📅 1988 🏛 American Chemical Society 🌐 English ⚖ 419 KB
N′-(Diphenylmethylene)-3-(3-nitrophenyl)
✍ Chakkaravarthi, G. ;Periyasamy, G. ;Raghunathan, R. ;Manivannan, V. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 616 KB

In the title compound, C~31~H~21~N~3~O~5~, the indan ring system makes dihedral angles of 53.26 (6) with the nitrobenzene ring, and 66.50 (6) and 58.39 (7)° with the two phenyl rings. The crystal packing is stabilized by weak intermolecular N—H...O and C—H...O hydrogen bonds.