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Synthesis of 1,1-Diarylethylenes via Efficient Iron/Copper Co-Catalyzed Coupling of 1-Arylvinyl Halides with Grignard Reagents

✍ Scribed by Hamze, Abdallah; Brion, Jean-Daniel; Alami, Mouad

Book ID: 120181176
Publisher: American Chemical Society
Year: 2012
Tongue: English
Weight: 406 KB
Volume: 14
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol3010112

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Efficient Synthesis of 1,1-Diaryl 1,2-Dienes via Pd(0)-Catalyzed Coupling of Aryl Halides with Allenic/Propargylic Zinc Reagents. -The title reaction is proposed to involve oxidative addition of halides to Pd(0) to form an organopalladium intermediate. This is trapped by an allenic or propargylic z