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ChemInform Abstract: Synthesis of 1,1-Diarylethylenes via Efficient Iron/Copper Co-Catalyzed Coupling of 1-Arylvinyl Halides with Grignard Reagents.

✍ Scribed by Abdallah Hamze; Jean-Daniel Brion; Mouad Alami


Book ID
115553019
Publisher
John Wiley and Sons
Year
2012
Weight
40 KB
Volume
43
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Efficient Synthesis
✍ Shengming Ma; Aibin Zhang πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 1 views

Efficient Synthesis of 1,1-Diaryl 1,2-Dienes via Pd(0)-Catalyzed Coupling of Aryl Halides with Allenic/Propargylic Zinc Reagents. -The title reaction is proposed to involve oxidative addition of halides to Pd(0) to form an organopalladium intermediate. This is trapped by an allenic or propargylic z