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Copper-Catalyzed Cross-Coupling Reaction of Grignard Reagents with Primary-Alkyl Halides: Remarkable Effect of 1-Phenylpropyne

✍ Scribed by Jun Terao; Hirohisa Todo; Shameem Ara Begum; Hitoshi Kuniyasu; Nobuaki Kambe

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
171 KB
Volume
46
Category
Article
ISSN
0044-8249

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Nickel-and palladium-catalyzed cross-coupling reactions of organic halides with organometallic reagents is one of the most versatile carbon±carbon bond-forming reactions in organic synthesis. [1] In most cases, aryl and vinyl halides are employed as organic halides, yielding sp 2 ±sp, sp 2 ±sp 2 , a