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Synthesis of 1-amino-2-vinylcyclopropane-1-phosphinates. Conversion of a phosphonate to phosphinates

โœ Scribed by Hyung-Jung Pyun; Michael O. Clarke; Aesop Cho; Anthony Casarez; Mingzhe Ji; Maria Fardis; Richard Pastor; X. Christopher Sheng; Choung U. Kim

Book ID
113930666
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
855 KB
Volume
53
Category
Article
ISSN
0040-4039

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Dibutyl ullylphosphonate can react with palladium chloride to give the dibutyl phosphorylated m-ally1 palladium chloride complex which was found to be able to react with a nucleophile, such as sodium dimethyl malonate, to give a functionalized 1 -alkenylphosphonate. A 1 -acetoxyallylic phosphonate c