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ChemInform Abstract: Synthesis of 1-Amino-2-vinylcyclopropane-1-phosphinates. Conversion of a Phosphonate to Phosphinates.

✍ Scribed by Hyung-Jung Pyun; Michael O. Clarke; Aesop Cho; Anthony Casarez; Mingzhe Ji; Maria Fardis; Richard Pastor; X. Christopher Sheng; Choung U. Kim

Book ID: 112049110
Publisher: John Wiley and Sons
Year: 2012
Weight: 47 KB
Volume: 43
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201234166

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Dibutyl ullylphosphonate can react with palladium chloride to give the dibutyl phosphorylated m-ally1 palladium chloride complex which was found to be able to react with a nucleophile, such as sodium dimethyl malonate, to give a functionalized 1 -alkenylphosphonate. A 1 -acetoxyallylic phosphonate c