Synthesis, DNA-binding and DNA-photocleavage properties of ruthenium(II) mixed-polypyridyl complex [Ru(tbz)2(dppz)]2+
✍ Scribed by Hui-Jie Shi; Yu Chen; Feng Gao; Hui-Juan Yu; Guan-Ying Li; Hui Chao; Xian-Fa Shi; Liang-Nian Ji
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 287 KB
- Volume
- 892
- Category
- Article
- ISSN
- 0022-2860
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## Abstract Polypyridyl ligand 9a,13a‐dihydro‐4,5,9,14‐tetraaza‐benzo[b]triphenylene‐11‐yl)‐phenyl‐methanone (BDPPZ) and its complexes [Ru(bpy)~2~BDPPZ]^2+^, [Ru(dmb)~2~BDPPZ]^2+^ and [Ru(phen)~2~BDPPZ]^2+^ (where bpy = 2,2′‐bipyridine, dmb = 4,4′‐dimethyl‐2,2′‐bipyridine, phen = 1,10‐phenanthrolin
DNA Binding, and DNA Photocleavage of the Ruthenium(II) Complexes [Ru(bpy)(btip)] 2+ and [Ru(dmb)(btip)] 2+ (bpy = 2,2'-Bipyridine; btip = 2-Benzo[b]thien-2-yl-1H-imidazo[4,5-f] [1,10]phenanthroline; dmb = 4,4'-Dimethyl-2,2'-bipyridine) by Li-Feng Tan\* a ), Fang Wang a ), and
## Abstract Two new complexes, [Ru(phen)~2~(ppd)]^2+^ (**1**) and [Ru(phen)(ppd)~2~]^2+^ (**2**) (ppd=pteridino[6,7‐__f__] [1,10]phenanthroline‐11,13(10__H__,12__H__)‐dione, phen=1,10‐phenanthroline) were synthesized and characterized by ES‐MS, ^1^H‐NMR spectroscopy, and elemental analysis. The int