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Synthesis, DNA Binding, and DNA Photocleavage of the Ruthenium(II) Complexes [Ru(bpy)(btip)]2+ and [Ru(dmb)(btip)]2+ (bpy = 2,2′-Bipyridine; btip = 2-Benzo[b]thien-2-yl-1H-imidazo[4,5-f] [1,10]phenanthroline; dmb = 4,4′-Dimethyl-2,2′-bipyridine)

✍ Scribed by Li-Feng Tan; Fang Wang; Hui Chao


Publisher
John Wiley and Sons
Year
2007
Tongue
German
Weight
166 KB
Volume
90
Category
Article
ISSN
0018-019X

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✦ Synopsis


DNA Binding, and DNA Photocleavage of the Ruthenium(II) Complexes [Ru(bpy)(btip)] 2+ and [Ru(dmb)(btip)] 2+ (bpy = 2,2'-Bipyridine; btip = 2-Benzo[b]thien-2-yl-1H-imidazo[4,5-f] [1,10]phenanthroline; dmb = 4,4'-Dimethyl-2,2'-bipyridine) by Li-Feng Tan* a ), Fang Wang a ), and


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## Abstract Two novel tridentate ruthenium(II) complexes containing an asymmetric heteroaromatic and a polyamine ligand, [Ru(dipn)(dptp)](ClO~4~)~2~ (**1**⋅2 $\rm{ ClO\_4^ -}$) and [Ru(dipn)(pat)](ClO~4~)~2~ (**2**⋅2 $\rm{ ClO\_4^ -}$) (dipn=__N__‐(3‐aminopropyl)propane‐1,3‐diamine; dptp=2‐(5,6‐dip