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Synthesis, crystal structure and third-order optical nonlinearity of a ‘flywheel’-shaped cluster, [MoS4Cu3(dppm)3][BF4]·2H2O

✍ Scribed by Weilian Tan; Hegen Zheng; Qionghua Jin; Guocheng Jin; Wei Ji; Deliang Long; Xinquan Xin

Book ID
108427922
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
105 KB
Volume
19
Category
Article
ISSN
0277-5387

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Synthesis, Crystal Structure and Third-order Nonlinear Optical Properties of Nest-shaped Cluster [CuBr(bpy)2] [MoOS3Cu3-Br2(bpy)]
✍ Ying-Lin Song; Hong-Wei Hou; Yao-Ting Fan; Chen-Xia Du; Yu Zhu 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 298 KB 👁 1 views

## Abstract Nest‐shaped cluster [CuBr(bpy)~2~][MoOS~3~Cu3Br~2~(bpy)] was synthesized by the treatment of (NH~4~)~2~ MOO~2~S~2~, CuBr and Et~4~NBr with bpy (2,2′‐bipyridyl) in CH~3~CN. Its structure has been characterized by X‐ray diffraction; monoclinic, space group __P__2~1~/__n__ ‐ with __a__ = l