Two novel two-dimensional (2D) lanthanide(III) coordination polymers [Ln(PDC)(OH)(H 2 O) 2 ] n (LnοΌEu (1) and Tb (2), H 2 PDCοΌpyridine-3,4-dicarboxylic acid) have been synthesized under hydrothermal conditions, and characterized by elemental analysis, IR, TGA and single-crystal X-ray diffraction. Bo
β¦ LIBER β¦
Synthesis, Crystal Structure, and Photophysical Properties of Novel (Monophthalocyaninato)lanthanide Complexes Stabilized by an Organometallic Tripodal Ligand
β Scribed by Hanzhong Ke; Wai-Kwok Wong; Wai-Yeung Wong; Hoi-Lam Tam; Chun-Ting Poon; Fenglei Jiang
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 444 KB
- Volume
- 2009
- Category
- Article
- ISSN
- 1434-1948
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## Abstract Three new lanthanide selenidoantimonates [Ln(en)~4~(SbSe~4~)] [Ln = La (1), Nd (2)] and [Sm(en)~4~]SbSe~4~Β·0.5en (3) (en = ethylenediamine) were first synthesized by treating LnCl~3~, Sb, and Se in a stoichiometric ratio with en under mild solvothermal conditions. Compounds 1 and 2 are