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Synthesis, Crystal Structure, and Photophysical Properties of Novel (Monophthalocyaninato)lanthanide Complexes Stabilized by an Organometallic Tripodal Ligand

✍ Scribed by Hanzhong Ke; Wai-Kwok Wong; Wai-Yeung Wong; Hoi-Lam Tam; Chun-Ting Poon; Fenglei Jiang


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
444 KB
Volume
2009
Category
Article
ISSN
1434-1948

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## Abstract Three new lanthanide selenidoantimonates [Ln(en)~4~(SbSe~4~)] [Ln = La (1), Nd (2)] and [Sm(en)~4~]SbSe~4~Β·0.5en (3) (en = ethylenediamine) were first synthesized by treating LnCl~3~, Sb, and Se in a stoichiometric ratio with en under mild solvothermal conditions. Compounds 1 and 2 are