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Synthesis, crystal structure and magnetic properties of the one-dimensional chain compound catena-poly[aquabis(4,4′-bis-1,2,4-triazole-N1) (thiocyanato-N)-manganese-μ-[4,4′-bis-1,2,4-triazole-N1,N1′]thiocyanate]

✍ Scribed by Carolien L. Zilverentant; Willem L. Driessen; Jaap G. Haasnoot; Jeroen J.A. Kolnaar; Jan Reedijk


Book ID
108331709
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
456 KB
Volume
282
Category
Article
ISSN
0020-1693

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catena-Poly[[bis[μ-1,4-bis(1,2,4-triazol
✍ Lin, Jin ;Dong, Gui-Ying 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 1014 KB

The crystal structure of the title compound, {[Cu(C 12 H 12 N 6 )]-ClO 4 } n , consists of a one-dimensional cationic copper(I) chain and uncoordinated ClO 4 À anions. In the cationic chain, the Cu I center, which lies on a crystallographic twofold rotation axis, is coordinated by two N atoms from t