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Synthesis, crystal, molecular and electronic structure of the [Re(NO)0.87Br2.13(PPh3)(PPh2py-P,N)] complex and DFT calculations of [Re(NO)Br2(PPh3)(PPh2py- P,N)]

✍ Scribed by B. Machura; R. Kruszynski


Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
492 KB
Volume
837
Category
Article
ISSN
0022-2860

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Reactions of Ag 4 X 4 (Ph 3 P) 4 (X = Br, I) with 1,3-bis(diphenylphosphine)methane (dppm) ligand under microwave heating conditions afforded two asymmetric silver(I) dimers of the type [Ag 2 (l-X) 2 (ldppm)(PPh 3 ) 2 ], X = Br(1), I(2), with butterfly-shaped dinuclear cores. The molecular structure