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Molecular octahedral sulfido-bromide rhenium clusters: Synthesis and crystal structure of (PPh4)2[Re6S6Br8] ∗d CH3C6H5 and (PPh4)3[Re6S7Br7]

✍ Scribed by Vladimir P. Fedin; Hideo Imoto; Taro Saito; Vladimir E. Fedorov; Yuri V. Mironov; Spartak S. Yarovoi


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
344 KB
Volume
15
Category
Article
ISSN
0277-5387

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Synthesis and Structure of [nPr3N(CH2)6N
✍ Andreas Eichhöfer; Dieter Fenske; Jolanta Olkowska-Oetzel 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 185 KB

## Abstract CuBr and Fe(OOCCH~3~)~2~ react with PhSeSiMe~3~ in acetonitrile in the presence of the diammonium salt [__n__Pr~3~N(CH~2~)~6~N__n__Pr~3~]Br~2~ to yield ionic [__n__Pr~3~N(CH~2~)~6~N__n__Pr~3~][CuFe~3~Br~3~(SePh)~6~]. The neutral complexes [Cu~5~Fe(SePh)~7~(PPh~3~)~4~] and [Cu~4~Fe~3~(Se