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New Rhenium Octahedral Cluster Sulfido-Cyanide Chain Polymer: The Synthesis and Crystal Structure of Cs4 [{Re6S8}(CN)4S2/2].

โœ Scribed by N. G. Naumov; S.-J. Kim; A. V. Virovets; Y. V. Mironov; V. E. Fedorov


Publisher
John Wiley and Sons
Year
2006
Weight
10 KB
Volume
37
Category
Article
ISSN
0931-7597

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Bis(disulfide) bridged Nb(+4) cluster halide complexes [Nb 2 S 4 X 8 ] 4ยฑ (X = Cl, Br) were prepared by acid hydrolysis of [Nb 2 S 4 (NCS) 8 ] 4ยฑ in concentrated aqueous HCl or HBr, solution from which they can be isolated as double salts Cs 5 [Nb 2 S 4 X 8 ]X (X = Cl, 1; X = Br, 2). The crystal st