Bis(disulfide) bridged Nb(+4) cluster halide complexes [Nb 2 S 4 X 8 ] 4± (X = Cl, Br) were prepared by acid hydrolysis of [Nb 2 S 4 (NCS) 8 ] 4± in concentrated aqueous HCl or HBr, solution from which they can be isolated as double salts Cs 5 [Nb 2 S 4 X 8 ]X (X = Cl, 1; X = Br, 2). The crystal st
✦ LIBER ✦
ChemInform Abstract: Synthesis and Crystal Structures of Cs5Nb2S4X9 — Double Salts Containing New Cluster Anions [Nb2(μ-S2)2X8]4- (X: Cl, Br).
✍ Scribed by Maxim Sokolov; Hideo Imoto; Taro Saito; Vladimir Fedorov
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 37 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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