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Synthesis, Conformational Analysis, and Biological-Activity of the 1-α,25-Dihydroxy-10,19-Dihydrovitamin D3 Isomers

✍ Scribed by R.R. Sicinski; H.F. Deluca

Book ID
102966039
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
1006 KB
Volume
22
Category
Article
ISSN
0045-2068

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Synthesis and Biological Evaluation of 1α,24-Dihydroxy-25nitrovitamin D 3 . -The synthesis of an active vitamin D 3 analogue (X), proceeding via palladium-catalyzed alkylative enyne reaction, is described. The corresponding 24(S)-isomer is found to be tenfold less potent than (X).