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Synthesis, characterization and crystal structure of [Cu(2-pic)2Br2][(2-picH)2]

✍ Scribed by Bogumiła Żurowska; Andrzej Kochel

Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
419 KB
Volume
877
Category
Article
ISSN
0022-2860

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The hydrothermal reactions of CuBr 2 , CuBr, and ethylenediamine have resulted in the synthesis of two new compounds. [Cu(H 2 NCH 2 CH 2 NH 2 ) 2 ] [{Cu 2 Br 4 }] has a two-dimensional sheet structure while [Cu(H 2 NCH 2 CH 2 NH 2 ) 2 ] [{Cu 5 Br 7 }] crystallizes as a three-dimensional network. Bot