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Synthesis, characterization and crystal structure of a novel 2D Cu(I) complex with flexible ligand

✍ Scribed by Jianqiang Liu; Yaoyu Wang; Weihong Zhang; Juncheng Jin; Mei Zhang; Qizhen Shi

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
167 KB
Volume
44
Category
Article
ISSN
0232-1300

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✦ Synopsis

Abstract

An exploration of the Cu(I)‐L system under hydrothermal conditions, has led to the isolation of a novel framework [Cu(I)(L)]~n~ (1) (L = bis(3,3‐dimethyl‐4,4‐dihydro‐1H‐pyrazol‐4‐yl)methane). Single‐crystal X‐ray analysis reveals that it crystallizes in the monoclinic, space group C2/c, a = 19.781(4) Å, b =11.026(3) Å, c = 16.339(4) Å, β = 127.186(3)°. The Cu ions are linked into an extended rainbow‐like chain via L molecules. Further, these adjacent chains are united together through hydrogen‐bonded interaction to a 2D layer. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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