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Synthesis, characterization and crystal structure of a 2D Cd(II) complex with a 4,4'-diazenediyldiphthalic acid ligand

✍ Scribed by Lu Lu; Jun Wang; Jian-Wei Bai; Yang Hou; Bin Yang; Bao-Zhong Zhao

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
204 KB
Volume
43
Category
Article
ISSN
0232-1300

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✦ Synopsis

An exploration of the cadmium-L system under hydrothermal condition, has led to the isolation of a novel framework {[Cd(L) 0.5 (H 2 O) 3 ]} n (1) (H 4 L = 4,4'-diazenediyldiphthalic acid). Single-crystal X-ray analysis reveals that it crystallizes in the triclinic space group P-1. a = 5.746(3) Å, b =6.526(4) Å, c = 14.701(8) Å, α=92.348(8)°, β = 99.622(6)°, γ=106.877(7)°. The Cd ІІ ions are linked into an extended 2-D rectangle-like structure via L ligands, which exhibits an attractive three-connected honeycomb topological network.

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