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Synthesis, characterization and crystal structure of a 3-D supramolecular Cu/Mn complex with pydc

✍ Scribed by Jian Wu

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
155 KB
Volume
43
Category
Article
ISSN
0232-1300

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✦ Synopsis

Abstract

A supramolecular compound, {[CuMn(pydc)~2~(H~2~O)~5~]·2H~2~O} (1) (pydc = pyridine‐2,6‐dicarboxylate dianion), has been synthesized and characterized by single‐crystal X‐ray diffraction. Single‐crystal X‐ray analysis reveals that it crystallizes in the triclinic space group P‐1, a = 8.4763(17) Å, b = 9.7715(19) Å, c = 13.909(3) Å, α =101.234(3)°, β =102.520(3)°, γ= 97.375(4)°. Two mixed‐metal ions exhibit similar coordinated geometries with octahedron. 1 possesses a 3‐D unusual supramolecular network featuring 1D water tape. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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