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Synthesis Based on Cyclohexadienes. 5. A New Approach to the Synthesis of a-Ring Aromatic Steroids - a Formal Total Synthesis of (+/-)-Estrone

โœ Scribed by Rao, GSRS; Banerjee, DK; Devi, LU; Sheriff, U

Book ID
111682244
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
1992
Tongue
English
Weight
1006 KB
Volume
45
Category
Article
ISSN
0004-9425

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Total synthesis of new steroids having a
Total synthesis of new steroids having an aromatic A ring with a 3-OH
โœ Philippe Maurin; Malika Ibrahim-Ouali; Maurice Santelli ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 78 KB

A new strategy for introducing an hydroxy group at the position 3 of an aromatic A ring in a steroid, which is a key position for biological purposes, is described. This procedure has required a judicious choice of a t-butyl ether as protective group at the beginning of the synthesis, and its deprot