ChemInform Abstract: Synthesis Based on Cyclohexadienes. Part 19. A New Total Synthesis of 2-Pupukeanone.
β Scribed by K. KALIAPPAN; G. S. R. S. RAO
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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Enantiospecific Total Synthesis of (+)-2-Pupukeanone. -The first enantiospecific total synthesis of 2-pupukeanone (X) starting from readily available (R)-carvone (I) is described. Key step in the synthetic sequence is the construction of the tricyclic isotwistane carbon framework via 5-exo-trig rad
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