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Synthesis applications of cationic aza-Cope rearrangements. 26. Enantioselective total synthesis of (-)-strychnine

✍ Scribed by Knight, Steven D.; Overman, Larry E.; Pairaudeau, Garry


Book ID
120982889
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
259 KB
Volume
115
Category
Article
ISSN
0002-7863

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Synthesis applications of aza-cope rearr
✍ Larry E Overman; E.Jon Jacobsen πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 226 KB

pyrroles can be prepared in stereocontrolled fashions by the reaction of 2-amino-l-(l-phenylvlnyl)cyclohexanols with formaldehyde and acid. Recent papers from our laboratory have described the use of "Mannich-directed" cationic aza-Cope rearrangements for the preparation of octahydroindolones by an