Synthesis and X-ray structure of cationic β-diimine palladium complexes containing π-methallyl ligand
✍ Scribed by Kamel Landolsi; Philippe Richard; Faouzi Bouachir
- Book ID
- 108187958
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 370 KB
- Volume
- 690
- Category
- Article
- ISSN
- 0022-328X
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Reaction of (1,2-dimethoxyethane)NiBr 2 a with b-iminoamines ligands c-f is reported and produces a series of paramagnetic complexes (b-diimine)NiBr 2 1c-f. Reduction in situ of compounds 1c-f in the presence of 2-methylallyloxyphosphonium salt 2 was found as a one-step synthesis of nickel allyl cat
New neutral organometallic palladium(II) complexes, obtained upon treating complexes of the type [PdRX(P ʝ N)] with PPh 3 and AgCF 3 SO 3 and consist predominantly of the [PdPhI(PNMe 2 )] (1), [PdPhI(PC=NMe)] (2), [PdPhI(PC=NEt)] (3), and [PdMeCl(PNMe 2 )] (4), {PNMe 2 means N,N-dimethyl-trans-P,P i