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Synthesis, X-ray Structure, and Reactivity of Phosphine-Substituted Iron Carbonyl Complexes Containing σ -Alkyl− π -Allyl Ligands

✍ Scribed by Jenny, Titus A.; Huber, Vroni; Ma, Liqian; Raemy, Jacques; Zeller, David; Stoeckli-Evans, Helen

Book ID
126126180
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
154 KB
Volume
21
Category
Article
ISSN
0276-7333

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## Abstract The monoalkyl complexes [Zr{Me~2~Si(η^5^‐C~5~Me~4~)(η^5^‐C~5~H~3~R)}(R′)Cl] [R = Me, R′ = CH~2~Ph (1); R = Me, R′ = CH~2~SiMe~3~ (2); R = __i__Pr, R′ = CH~2~Ph (3); R = __i__Pr, R′ = CH~2~SiMe~3~ (4); R = SiMe~3~, R′ = CH~2~Ph (5); R = SiMe~3~, R′ = CH~2~SiMe~3~ (6)] have been synthesiz