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Synthesis and thermal stability of silicon-containing esters of phosphorus acids

✍ Scribed by L. S. Zakharov; G. N. Molchanova; T. M. Shcherbina; P. V. Petrovskii; M. I. Kabachnik


Publisher
Springer
Year
1998
Tongue
English
Weight
538 KB
Volume
47
Category
Article
ISSN
1573-9171

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ChemInform Abstract: Synthesis and Therm
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

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## Abstract S‐(Diethylamino)dimethylsilyl bis(diethylamido)dithiophosphate **3** was obtained by the reaction of tetraphosphorus decasulfide **1** with bis(diethylamino)dimethylsilane **2a**. The reactions of Lawesson's reagent **5** with **2a** and the alkyl homologues of Davy's reagent **8a,b** w

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Phosphorus-, silicon-and chlorine-containing oligomers were synthesized by the dealkylation of methyl esters of phosphonic and phosphoric acids with dimethyldichlorsilane or diphenyldichlorsilane. It was established that the ,,-carbon atom of the methoxy group acts as an electrophilic centre. The st