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Synthesis and thermal decomposition reaction kinetics of complexes of [Sm2(m-ClBA)6(phen)2] · 2H2O and [Sm2(m-BrBA)6(phen)2] · 2H2O

✍ Scribed by Jian Jun Zhang; Ning Ren; Ji Hai Bai; Su Ling Xu

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
169 KB
Volume
39
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

Complexes of [Sm~2~(m‐ClBA)~6~(phen)~2~] · 2H~2~O and [Sm~2~(m‐BrBA)~6~(phen)~2~] · 2H~2~O (m‐ClBA = m‐chlorobenzoate, m‐BrBA = m‐bromobenzoate, and phen = 1,10‐phenanthroline) were prepared and characterized by elemental analysis and IR spectra. The thermal decomposition processes of the two complexes were studied by means of TG–DTG and IR techniques. Their thermal decomposition kinetics were investigated from the analysis of the TG and DTG curves by jointly using a new method proposed by us and a newly nonlinear isoconversional integral method. © 2006 Wiley Periodicals, Inc. Int J Chem Kinet 39: 67–74, 2007

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