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Synthesis and study ofN-(1-phenylethylidene)-N-(4H-1,2,4-triazol-4-yl)amine,N′-(4H-1,2,4-triazol-4-yl)benzamidine, and cobalt(ii), nickel(ii), and copper(ii) complexes based on these ligands

✍ Scribed by E. V. Lider; E. V. Peresypkina; K. A. Volkova; E. V. Abramova; Yu. G. Shvedenkov; V. N. Ikorskii; L. A. Sheludyakova; A. I. Smolentsev; L. G. Lavrenova

Publisher
Springer
Year
2008
Tongue
English
Weight
573 KB
Volume
57
Category
Article
ISSN
1573-9171

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Probing the Dinucleating Behaviour of a
Probing the Dinucleating Behaviour of a Bis-Bidentate Ligand: Synthesis and Characterisation of Some Di- and Mononuclear Cobalt(II), Nickel(II), Copper(II) and Zinc(II) Complexes of 3,5-Di(2-pyridyl)-4-(1H-pyrrol-1-yl)-4H-1,2,4-triazole
✍ Marco H. Klingele; Peter D. W. Boyd; Boujemaa Moubaraki; Keith S. Murray; Sally 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 292 KB

## Abstract As a probe of the dinucleating ability of the known but little studied bis‐bidentate ligand 3,5‐di(2‐pyridyl)‐4‐(1__H__‐pyrrol‐1‐yl)‐4__H__‐1,2,4‐triazole (pldpt) its reactivity towards MX~2~·6H~2~O (M = Co^II^, Ni^II^ and Zn^II^; X = ClO~4~^–^ and BF~4~^–^) as well as Cu(ClO~4~)~2~·6H~

First Complexes of a 4-Alkyl-3,5-di(2-py
First Complexes of a 4-Alkyl-3,5-di(2-pyridyl)-4H-1,2,4-triazole: Synthesis,X-ray Crystal Structures and Magnetic Properties of Dinuclear Cobalt(II), Nickel(II) and Copper(II) Complexes of 4-Isobutyl-3,5-di(2-pyridyl)-4H-1,2,4-triazole
✍ Marco H. Klingele; Peter D. W. Boyd; Boujemaa Moubaraki; Keith S. Murray; Sally 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 182 KB 👁 1 views

## Abstract The reaction of the new, bis(bidentate), potentially dinucleating ligand 4‐isobutyl‐3,5‐di(2‐pyridyl)‐4__H__‐1,2,4‐triazole (ibdpt) with M(ClO~4~)~2~·6H~2~O (M = Co^II^, Ni^II^ or Cu^II^) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co^II^~2~(ibdpt)~2~(MeCN)~2~(H~2~O)~2~