Synthesis and study of physicochemical properties of the magnesium heteropoly compound (NH4)4[MgMo6O18(OH)6] · 5H2O
✍ Scribed by A. V. Oreshkina; G. Z. Kaziev; N. N. Lobanov; A. V. Steblevskii
- Book ID
- 114989946
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2012
- Tongue
- English
- Weight
- 375 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0036-0236
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Large single crystals of the polar, hydrated pentaborates Me[B 5 O 6 (OH) 4 ]•2H 2 O (Me = Rb, NH 4 ) were grown from aqueous solutions. The structure of NH 4 [B 5 O 6 (OH) 4 ]•2H 2 O was redetermined and proved to be orthorhombic (space group Aba2 (No. 41) with a = 11.3192(7) Å, b = 11.0261(8) Å, c
## Abstract Red large single crystals of the new title compound are prepared from an aqueous solution of H~3~BO~3~, CoCl~2~, and NH~4~OH (pH 9, 25 °C, 3 d).
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