## Abstract Red large single crystals of the new title compound are prepared from an aqueous solution of H~3~BO~3~, CoCl~2~, and NH~4~OH (pH 9, 25 °C, 3 d).
Synthesis, Crystal Structure and Vibrational Spectroscopy of NH4 [Co(NH3)5 (H2O)][B4O5 (OH)4]2·6H2O
✍ Scribed by Dan Lin; Xiaoyan You; Lixia Zhu; Qin Xiao
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 182 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0256-7660
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Large single crystals of the polar, hydrated pentaborates Me[B 5 O 6 (OH) 4 ]•2H 2 O (Me = Rb, NH 4 ) were grown from aqueous solutions. The structure of NH 4 [B 5 O 6 (OH) 4 ]•2H 2 O was redetermined and proved to be orthorhombic (space group Aba2 (No. 41) with a = 11.3192(7) Å, b = 11.0261(8) Å, c