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Synthesis and Structures of the Novel Manganese(−I) Fullerene-[60] Complexes M[Mn(CO) 4 (η 2 -C 60 )] (M = Na, PPN)

✍ Scribed by Bengough, Michael N.; Thompson, David M.; Baird, Michael C.; Enright, Gary D.


Book ID
126267466
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
47 KB
Volume
18
Category
Article
ISSN
0276-7333

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✍ Li-Cheng Song; Peng-Chong Liu; Jin-Ting Liu; Fu-Hai Su; Guang-Feng Wang; Qing-Me 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 245 KB

## Abstract This paper reports on several new optically active organometallic [60]fullerene complexes that contain a chiral (+)‐DIOP or (−)‐DIOP ligand [DIOP = 2,3‐__O__,__O′__‐isopropylidene‐2,3‐dihydroxy‐1,4‐bis(diphenylphosphanyl)butane]. The Mo/W complexes __mer__‐[(η^2^‐C~60~)M(CO)~3~{(−)‐DIOP