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Synthesis and Crystal Structures of Two Isomerically Pure Organotransition-Metal [60]Fullerene Derivatives Containing dppb Ligands: mer -M(CO) 3 (dppb)(η 2 -C 60 ) (M = Mo, W)

✍ Scribed by Song, Li-Cheng; Liu, Jin-Ting; Hu, Qing-Mei; Weng, Lin-Hong


Book ID
125973229
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
109 KB
Volume
19
Category
Article
ISSN
0276-7333

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Synthesis, Characterization and Electroc
✍ Li-Cheng Song; Peng-Chong Liu; Jin-Ting Liu; Fu-Hai Su; Guang-Feng Wang; Qing-Me 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 245 KB

## Abstract This paper reports on several new optically active organometallic [60]fullerene complexes that contain a chiral (+)‐DIOP or (−)‐DIOP ligand [DIOP = 2,3‐__O__,__O′__‐isopropylidene‐2,3‐dihydroxy‐1,4‐bis(diphenylphosphanyl)butane]. The Mo/W complexes __mer__‐[(η^2^‐C~60~)M(CO)~3~{(−)‐DIOP