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Synthesis and Structures of Homoleptic Methyl- and Phenylthiomethylaluminium Complexes [Al(CH2SR)3](R = Me, Ph)

✍ Scribed by Tobias Rüffer; Clemens Bruhn; Eduard Rusanov; Karsten Nordhoff; Dirk Steinborn


Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
451 KB
Volume
628
Category
Article
ISSN
0372-7874

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✍ Wolfgang Malisch; Marco Hofmann; Martin Nieger; Wolfgang W. Schöller; Andreas Su 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 264 KB 👁 3 views

The novel (ferriomethyl)-substituted silanols C 5 R 5 (OC) 2 Fe-CH 2 -SiMe(RЈ)OH [R = H, RЈ = Me (4a), Ph (4b); R = Me, RЈ = Me (4c)] are obtained by hydrolysis of the chloro(ferriomethyl)silanes C 5 R 5 (OC) 2 Fe-CH 2 -SiMe(RЈ)Cl [R = H, RЈ = Me (3a), Ph (3b); R = Me, RЈ = Me (3c)] in the presence