Synthesis and structural characterization of the electron rich complexes Co(η-C5Me5)(R2PCH2CH2PR2) (R = Me, Ph); photoelectron spectroscopic studies of some pentamethylcyclopentadienylphosphinecobalt complexes
✍ Scribed by Nicholas Dudeney; Jennifer C. Green; Peter Grebenik; Olaf N. Kirchner
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 616 KB
- Volume
- 252
- Category
- Article
- ISSN
- 0022-328X
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The novel (ferriomethyl)-substituted silanols C 5 R 5 (OC) 2 Fe-CH 2 -SiMe(RЈ)OH [R = H, RЈ = Me (4a), Ph (4b); R = Me, RЈ = Me (4c)] are obtained by hydrolysis of the chloro(ferriomethyl)silanes C 5 R 5 (OC) 2 Fe-CH 2 -SiMe(RЈ)Cl [R = H, RЈ = Me (3a), Ph (3b); R = Me, RЈ = Me (3c)] in the presence
## Abstract The reaction of the vinylidene complexes [(C~5~H~5~)(CO)(NO)W=C=C(H)R] (10a: R = __t__Bu; 10b: R = Ph) with the arsaalkene __t__BuC(O)–As=C(NMe~2~)~2~ (11) afforded the novel η^2^‐1‐arsaallene complexes [η^2^‐{__t__BuC(O)–As=C=C(H)R}W(CO)(NO)C~5~H~5~] (13: R = __t__Bu; 15: R = Ph). Simi