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Synthesis and structures of free and coordinated phosphaalkenes

✍ Scribed by Cowley, A. H.; Jones, R. A.; Lasch, J. G.; Norman, N. C.; Stewart, C. A.; Stuart, A. L.; Atwood, J. L.; Hunter, W. E.; Zhang, H. M.

Book ID
126970325
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
730 KB
Volume
106
Category
Article
ISSN
0002-7863

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tive towards S8, CH2N2, Fez(C0)9, and CS,; 1Oa-c and 11 are formed. Variable temperature 'H-NMR spectro-10 11 a , X = S ; b, X = CHZ; c , X = F e ( C 0 ) 4 scopic studies on 10a-c indicate that a rapid "olefinlike" rotation of the (Me2N)2P-X moiety occurs[' 'I.